Potassium polyacrylate (PAAK) with the low molecular weight was synthesized by aqueous solution polymerization, and it was used as an organic flame suppressant to prepare single-based propellant. Potassium content in PAAK was tested by a flame atomic absorption spectrometry, and intrinsic viscosity was measured by a Ubbelohde viscometer. Compatibility of PAAK with nitrocellulose (NC) was investigated by DSC method, and combustion residues of single-based propellant containing PAAK, KNO3 or K2SO4 were compared by nitrogen-bomb method. The results show that mass fraction of potassium in PAAK is 15.21%, and the molecular weight is about 3 000, which is beneficial to mix with NC uniformly. It has a good compatibility with NC in neutral or slightly alkaline (pH=7.0-7.5). Compared with single-based propellant containing KNO3 or K2SO4, the single-based propellant containing PAAK is homogeneous and transparent due to PAAK being evenly mixed NC. Combustion residue of PAAK propellant is the least, accounting for 0.18% of the mass of propellant.
SONG Yufang;XIAO Leqin;JIAN Xiaoxia;ZHOU Weiliang.
Synthesis of Potassium Polyacrylate with Low Molecular Weight and Its Application. Explosive Materials. 2019, 48(5): 40-45 https://doi.org/10.3969/j.issn.1001-8352.2019.05.008