低分子量聚丙烯酸钾的合成及其应用

宋育芳;肖乐勤;菅晓霞;周伟良

爆破器材 ›› 2019, Vol. 48 ›› Issue (5) : 40-45.

爆破器材 ›› 2019, Vol. 48 ›› Issue (5) : 40-45. DOI: 10.3969/j.issn.1001-8352.2019.05.008
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低分子量聚丙烯酸钾的合成及其应用

  • 宋育芳,肖乐勤,菅晓霞,周伟良
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Synthesis of Potassium Polyacrylate with Low Molecular Weight and Its Application

  • SONG Yufang, XIAO Leqin, JIAN Xiaoxia, ZHOU Weiliang
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摘要

采用水溶液聚合法制备了低分子量聚丙烯酸钾(PAAK),并作为新型消焰剂加入单基发射药中。通过火焰原子吸收光谱法测试了PAAK中钾的含量;用乌氏黏度计测定了特性黏度;采用DSC法研究不同pH值的PAAK与硝化棉(NC)的相容性;利用充氮氧弹法对添加PAAK、硝酸钾KNO3、硫酸钾K2SO4的单基发射药的燃烧残渣进行了对比研究。结果表明,合成的PAAK中,钾的质量分数为15.21%,相对分子量在3 000左右,有利于和NC均匀混合,且在中性或微碱性(pH=7.0~7.5)的情况与NC相容性良好。与传统的KNO3、K2SO4消焰剂相比,PAAK能够和NC均匀混合,制备均质透明的单基发射药;PAAK发射药的燃烧残渣最少,占发射药质量的0.18%。

Abstract

Potassium polyacrylate (PAAK) with the low molecular weight was synthesized by aqueous solution polymerization, and it was used as an organic flame suppressant to prepare single-based propellant. Potassium content in PAAK was tested by a flame atomic absorption spectrometry, and intrinsic viscosity was measured by a Ubbelohde viscometer. Compatibility of PAAK with nitrocellulose (NC) was investigated by DSC method, and combustion residues of single-based propellant containing PAAK, KNO3 or K2SO4 were compared by nitrogen-bomb method. The results show that mass fraction of potassium in PAAK is 15.21%, and the molecular weight is about 3 000, which is beneficial to mix with NC uniformly. It has a good compatibility with NC in neutral or slightly alkaline (pH=7.0-7.5). Compared with single-based propellant containing KNO3 or K2SO4, the single-based propellant containing PAAK is homogeneous and transparent due to PAAK being evenly mixed NC. Combustion residue of PAAK propellant is the least, accounting for 0.18% of the mass of propellant.

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宋育芳;肖乐勤;菅晓霞;周伟良. 低分子量聚丙烯酸钾的合成及其应用. 爆破器材. 2019, 48(5): 40-45 https://doi.org/10.3969/j.issn.1001-8352.2019.05.008
SONG Yufang;XIAO Leqin;JIAN Xiaoxia;ZHOU Weiliang. Synthesis of Potassium Polyacrylate with Low Molecular Weight and Its Application. Explosive Materials. 2019, 48(5): 40-45 https://doi.org/10.3969/j.issn.1001-8352.2019.05.008
中图分类号: TQ569   

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